Novel materials
with unique properties drive the evolution of numerous fields and the
development of exciting new devices. A new class of materials,
plasmonics, exploits the interaction of light with composites consisting
of metals and dielectrics to produce optical properties not seen in
nature. These metamaterials are expected to enhance the performance of
many optoelectronic devices but applicability has remained elusive.
The EU-funded project 'Plasmonically-enhanced quantum dot
photodetectors' (PEQUPHOT) was launched to break the barrier and
demonstrate the potential. It combined two novel technologies, a type of
nanostructured (quantum dot) photodetector and a plasmonic antenna.
The team chose photodetectors as detection of optical signals is
critical to numerous applications. Low-cost, solution-processed quantum
dot photodetectors are gaining interest. However, there has been a
trade-off between speed and sensitivity. Minimising the electrically
active area increases speed but the optically active area must be large
enough to capture a lot of photons. Plasmonic antennae concentrate light
at the nanoscale, providing the impetus for the project.
Scientists employed a plasmonic bull's eye structure that consists
of periodically arranged concentric metal grooves. The grooves
concentrate and focus the light into the centre or bull's eye, enhancing
transmission through a sub-wavelength hole there. They thus reduced the
electrically active area of the photodetector but maintained its
optically active area with a plasmonic antenna. Experiments demonstrated
that the performance of the quantum dot photodetectors was improved. In
fact, the plasmonic bull's eye photodetector outperformed both
references.
PEQUPHOT has provided compelling new evidence that plasmonics can
enhance the performance of optoelectronic devices. The project has made a
major contribution to a growing field and strengthened the EU's
competitive position.